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The wires need to be clean in order to make a good joint. A little extra flux from a flux pen never does any harm and often makes it easier if the insulation has not been freshly removed. In the case of enamelled wire, the enamel needs to be scraped or burnt off. If a little remains it often won't matter and may melt with the solder. In fact some wire enamels are "solder-through" and designed to melt with the solder, but an initial scrape to get it started usually helps.